Hey Matthew, sorry for the delay in responding, I thought more of the NC hunters here would respond - there are several NC hunting threads and the older one can give you a good idea what to expect.
Being from PA myself with a hunting camp for 10 years in the Alleghany National Forest, I have killed bears, turkeys and deer in PA before moving to NC; been here for 5 years now. I suspect that you might be a little disappointed with the NC hunting compared to PA, but there are some pleasant surprises too. I don't know Rutherford county like Dennis (by the way, he is a great guy and you should take him up on his offer to help), but I would rate the deer hunting quality in NC as much lower (much less bowhunting pressure though, the season started already, and you can kill more than 1 buck), the turkey hunting quality as lower but not by too much, and the bear hunting as better (because the season runs much longer and there are plenty of bears, and lots of BIG bears, especially along the coast (although as a bowhunter, you should know that probably 90-95% of the bears are killed with dogs). Now for the pleasant surprises, you can hunt feral hogs in NC on a limited basis (forget the ones by the Smokies, unless you hunt with dogs) over towards the coast, and unlike PA you can hunt some interesting coastal areas that are pretty unique.
Hope this helps.