I understand folks comments on hunting shots and agree...but the question is about shooting in general I think.
Given that, shooting trad gear is no different than shooting any other hunting weapon. All good shooters have a good mental game, form, aiming skills, and clean release.
When the hunting shot comes, my hope is that most of those are committed to muscle memory, but to get to that spot, you cannot bypass good techniques and practice.
Also, I do not believe that trad shooting is easy or we over think it. Throwing an arrow is easy. Shooting one well - over and over - is not.