I believe nhbuck is correct. Your tab is clearly hitting your face, and is probably too large. I can see that you have a good release where you are relaxing your fingers rather than opening them, so you should be able to use a tab that is cut shorter than your fingertips. I have to congratulate you on not flinching away in anticipation of the tab hitting your face, painful though it may be. I looked very carefully for head movement before release, and didn't see any.
What I couldn't see is your alignment. You need to have good straight alignment of your string forearm with your arrow to avoid hitting your face with your string or tab. Have someone stand behind you and put an arrow on your shoulder blades when you are at full draw. Is it pointing at the target? Video yourself from above and behind and make sure your drawing forearm is in line with the arrow.
Once this starts, it becomes a vicious cycle, because your skin becomes much more sensitive when it has been rubbed raw. A certain amount of skin contact is inevitable when you shoot the bow, and normally you just ignore it or your skin just toughens up. It probably would be a good idea to hold your hand far enough away from your face for a while to let it heal, so it isn't a constant irritation every time you shoot the bow.