Guys,just a little tip on molding with silicone caulk.If you add a few drops of water based paint like latex or acrylic and mix it in thoroughly,it will act as a catalyst and cause the silicone to set up in a few minutes.You could use the mold in about an hour.
Experiment with a small batch first.Use a color that shows up well so you can tell when it is well mixed.Don't waste time as it can set fast.I would start with about 2 drops of paint per oz of caulk and see how it goes.
When it feels set up on the outside,it will be set up all the way through.Without a catalyst,it could feel set on the outside but be sticky against the bark.
Don't sweat bark in the mold.As James said,it will imbed itself in your first cast.
Try the paint.You will be surprised.If it sets very fast,you may have to mix and apply 2 batches.Just make sure it is cured well before pulling from the tree.You can test a small piece at the edge to see if it wants to tear easily.