When adding reflex to a bow I start at the handle and work out each limb, separately, is small sections and clamp each section as I go. When done with one limb I start at the handle and work out the other limb. I can usually get the entire bow reflexed in an hour or less, depending on how much other straightening it needs.
I have tried clamping a stave to a caul and placing it in a hot,up to 186deg(F) that the thermostat allows and holding at that temp for a few hours. Then let it slowly cool over night. I have had limited results with this method and don't use it any more.