I've used Smooth On in bows for 20 years, many in part or whole that were glued up at room temps, and used them in hotter weather in the summer, and never saw any indication of the glue 'breaking down'.
No, I've never had an issue with the riser joints, but I wouldn't exactly say I don't worry about it. I simply worry about it to the extent that I'm mindful of the gluing surface prep, usually prepping the riser pieces with coarse grit belts or drums or grooving with a toothing plane blade so that it's impossible to starve a joint of glue, keep surfaces clean and free of contaminants or fingerprints, mix glue thoroughly, and usually I cure with some sort of heat. I've found that if I use good gluing practices, I don't need to worry.