I know you're excited, but I would wait on any major purchases until you hear others chime in.
If anyone can get close to deer, it's the guys on this site--and there have been many a discussion about hunter orange here.
My personal opinion is it is motion and pattern that sets you off while you're in orange...unless it is super cheap crap and full of UV brighteners (which orange tends to have), but I've had deer on me while in a full Columbia parka (solid), that had not a clue....
Actually, if memory serves, I read more comments about deer NOT seeing orange than guys complaining of being busted because they wore it.
Now the confidence factor has its merit...and I agree with Frank, and so does the input from lots of people here.
Take Care,
Marc