My deer sightings and shot opportunities for does and small bucks are about equally split began morning and evening. My biggest bucks have all been taken in the mid afternoon, between 1 & 3, during the late November rut. That said, I hunt every chance I get the time, and hunt as long as I can take the cold. Every year, my biggest buck sightings during tge rut are early afternoon, between 12-3. Reflecting back, I should hunt most of the day during the rut, taking a break between 10:30 and 12:00, which has been the least productive time where I hunt. The two months leading up to the rut, the first and last hour of light are the best times to hunt.